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Friday, September 8, 2017

How to differentiate between untreated tenebrescent scapolite and Irradiated tenebrescent scapolite . Case for study

Examination of Untreated Tenebrescent Scapolite and comparison with (newly)
 irradiated Tenebrescent Scapolite

By Hamid Usman Khattak (HUK)-Accredited  Gemologist

Introduction

Tenebrescence, also known as reversible photochromism, is the ability of minerals to change colour when exposed to sunlight. The effect can be repeated for an unlimited or unspecified period of time, but is destroyed by heating.

Tenebrescent Scapolite was first found in Badakshan, province ofAfghanistan in 2005. This unique colorless material is mined near the Hackmanite deposits and changes an aquamarine colorwhen exposed to LW/SW UV light.  This change of color is depending upon the time it has exposed to Ultra violet light. This change of color is not permanent it faded gradually almost in 30 seconds (Depending the lighting condition).
Note: In tungsten light tenebrescent scapolite faded its color very quickly but in fluorescent light the change in color is slowly.

Natural colorless tenebrescent scapolite



Natural colorless tenebrescent scapolite
Aim of the Experiment:  Gems & Gemological Institute of Pakistan (GGIP)-Peshawar recently identified a number of tenebrescent scapolite that have undergone irradiation treatment. The effect of these Tenebrescent scapolite in UV are unusual, duration of tenebresencent are prolonged and colored are more intense than Untreated scapolite. During microscopic study deformation and twist in inclusions are observe.
Details of the Experiment
•For this experiment I (HUK) selected 6 cut and polished colorless scapolite.  2 pieces (fig#1) are left behind untreated and Small 4 pieces (Fig#2) are further chosen for irradiation treatment.


  After Irradiation the color of the scapolite is unchanged but 3 type of changes are observe
1.Fluorescence effect
2.Effect on Tenebrescent duration and color intensity
3.Inclusions

   With the help of these three types of changes, gemologist  and trade people can easily identify in between the untreated tenebrescent scapolite and irradiated tenebrescent scapolite.

1.Fluorescence effect

•It is observed that irradiated scapolite show dull fluoresce effect in LW/SW as compare to untreated scapolite.

2. Effect on Tenebrescent duration and color intensity
  Untreated tenebrescent scapolite fades its color in almost 30 seconds
                                         but

      It is observed that the scapolite which are irradiated have tenebrescent property for prolong period (depend on environment) and color intensity is very dark blue (Kashmir sapphire color, Fig#6 & Fig#7). At normal room light (energy saver bulbs, Tube light) it duration is up to for 2 hour to 15 hours (depend on light condition) and gradually the stone color changes from dark blue to colorless. If the irradiated stones are placed in diamond parcel or in strongbox or in dark room then upto 1 month the blue color exist in the stones(Fig#8). It is also observed that the stone are more quickly fade in Tungsten light as compare to fluorescence light (energy saver bulbs or tube light).





3. Inclusions:

•Inclusions are very helpful in detection of irradiated scapolite. In irradiation scapolite mostly the inclusions are deform or twist.











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